Inorganic Frameworks for Electrification and Fuel Production

Welcome!

The McNicholas lab is a physical inorganic and materials group interested in both electrochemical and catalytic applications as well as fundamental electronic structure. We use a combination of spectroscopic and electrochemical techniques to develop and characterize next-generation energy conversion and storage technologies. We are particularly interested in two promising energy storage architectures:

---Monovalent and multivalent cation batteries employing metal inorganic framework cathodes and anodes

---Non-aqueous redox flow batteries employing homogeneous or heterogeneous multi-electron transfer electrolytes

Additionally, the development of more efficient and stable catalysts for small molecule reduction and oxidation, specifically those related to photoelectrochemical water oxidation, fuel cell technology, CO2 reduction, and N2 fixation, is an active area of research.

Finally, our group is also interested in the fundamental electronic structure of porphyrinoids and charge transfer complexes.

Our students develop a strong background in molecular and solid-state inorganic chemistry, with particular focus on electrochemical techniques, molecular and materials synthesis, computational chemistry, and spectroscopic techniques, including magnetic circular dichroism, X-ray absorption and emission, Raman, and spectroelectrochemistry.